A koordinációs szféra szimmetriájának meghatározása di-n-butilón(IV)2+ merkapto-karbonsavakkal képzett komplexeiben

Translated title of the contribution: Symmetry of the co-ordination sphere of di-n-butyltin(IV) in complexes with sulfanylcarboxylic acids

K. Gajda-Schrantz, László Nagy, E. Kuzmann, A. Vértes, Jan Holeček, Antonin Lyčka

Research output: Contribution to journalArticle

Abstract

Four di-n-butyltin(IV) complexes have been prepared with sulfanylacetic, 2-sulfanylpropionic, sulfanylsuccinic and m-2,3-disulfanylsuccinic acid, using two different procedures. The compounds were characterised by elemental analysis, Fourier-transform IR, Raman, 119Sn Mössbauer, 1H, 13C and 119Sn NMR spectroscopy. The IR and Raman data indicate the presence of bidentate carboxylate groups, non linear C-Sn-C bonds, and Sn-S bonds. The results of Mössbauer spectroscopic measurements, based on point-charge model calculations, have shown the general occurrence of trigonal-bipyramidal environments at tin(IV). The multinuclear NMR studies also suggested the {O,S} co-ordination of di-n-butyltin(IV) fragment, within the cyclic oligomeric complexes.

Original languageHungarian
Pages (from-to)477-487
Number of pages11
JournalMagyar Kemiai Folyoirat, Kemiai Kozlemenyek
Volume106
Issue number12
Publication statusPublished - 2000

Fingerprint

Acids
Tin
Nuclear magnetic resonance spectroscopy
Fourier transforms
Nuclear magnetic resonance
Chemical analysis
di-n-butyltin

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

A koordinációs szféra szimmetriájának meghatározása di-n-butilón(IV)2+ merkapto-karbonsavakkal képzett komplexeiben. / Gajda-Schrantz, K.; Nagy, László; Kuzmann, E.; Vértes, A.; Holeček, Jan; Lyčka, Antonin.

In: Magyar Kemiai Folyoirat, Kemiai Kozlemenyek, Vol. 106, No. 12, 2000, p. 477-487.

Research output: Contribution to journalArticle

@article{e1bf2adad9ec4e21b3bcd3a5af9d0226,
title = "A koordin{\'a}ci{\'o}s szf{\'e}ra szimmetri{\'a}j{\'a}nak meghat{\'a}roz{\'a}sa di-n-butil{\'o}n(IV)2+ merkapto-karbonsavakkal k{\'e}pzett komplexeiben",
abstract = "Four di-n-butyltin(IV) complexes have been prepared with sulfanylacetic, 2-sulfanylpropionic, sulfanylsuccinic and m-2,3-disulfanylsuccinic acid, using two different procedures. The compounds were characterised by elemental analysis, Fourier-transform IR, Raman, 119Sn M{\"o}ssbauer, 1H, 13C and 119Sn NMR spectroscopy. The IR and Raman data indicate the presence of bidentate carboxylate groups, non linear C-Sn-C bonds, and Sn-S bonds. The results of M{\"o}ssbauer spectroscopic measurements, based on point-charge model calculations, have shown the general occurrence of trigonal-bipyramidal environments at tin(IV). The multinuclear NMR studies also suggested the {O,S} co-ordination of di-n-butyltin(IV) fragment, within the cyclic oligomeric complexes.",
author = "K. Gajda-Schrantz and L{\'a}szl{\'o} Nagy and E. Kuzmann and A. V{\'e}rtes and Jan Holeček and Antonin Lyčka",
year = "2000",
language = "Hungarian",
volume = "106",
pages = "477--487",
journal = "Magyar Kemiai Folyoirat, Kemiai Kozlemenyek",
issn = "1418-9933",
publisher = "Magyar Kemikusok Egyesulete/Hungarian Chemical Society",
number = "12",

}

TY - JOUR

T1 - A koordinációs szféra szimmetriájának meghatározása di-n-butilón(IV)2+ merkapto-karbonsavakkal képzett komplexeiben

AU - Gajda-Schrantz, K.

AU - Nagy, László

AU - Kuzmann, E.

AU - Vértes, A.

AU - Holeček, Jan

AU - Lyčka, Antonin

PY - 2000

Y1 - 2000

N2 - Four di-n-butyltin(IV) complexes have been prepared with sulfanylacetic, 2-sulfanylpropionic, sulfanylsuccinic and m-2,3-disulfanylsuccinic acid, using two different procedures. The compounds were characterised by elemental analysis, Fourier-transform IR, Raman, 119Sn Mössbauer, 1H, 13C and 119Sn NMR spectroscopy. The IR and Raman data indicate the presence of bidentate carboxylate groups, non linear C-Sn-C bonds, and Sn-S bonds. The results of Mössbauer spectroscopic measurements, based on point-charge model calculations, have shown the general occurrence of trigonal-bipyramidal environments at tin(IV). The multinuclear NMR studies also suggested the {O,S} co-ordination of di-n-butyltin(IV) fragment, within the cyclic oligomeric complexes.

AB - Four di-n-butyltin(IV) complexes have been prepared with sulfanylacetic, 2-sulfanylpropionic, sulfanylsuccinic and m-2,3-disulfanylsuccinic acid, using two different procedures. The compounds were characterised by elemental analysis, Fourier-transform IR, Raman, 119Sn Mössbauer, 1H, 13C and 119Sn NMR spectroscopy. The IR and Raman data indicate the presence of bidentate carboxylate groups, non linear C-Sn-C bonds, and Sn-S bonds. The results of Mössbauer spectroscopic measurements, based on point-charge model calculations, have shown the general occurrence of trigonal-bipyramidal environments at tin(IV). The multinuclear NMR studies also suggested the {O,S} co-ordination of di-n-butyltin(IV) fragment, within the cyclic oligomeric complexes.

UR - http://www.scopus.com/inward/record.url?scp=84897832182&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84897832182&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:84897832182

VL - 106

SP - 477

EP - 487

JO - Magyar Kemiai Folyoirat, Kemiai Kozlemenyek

JF - Magyar Kemiai Folyoirat, Kemiai Kozlemenyek

SN - 1418-9933

IS - 12

ER -