Surface chemistry studies on molybdena-alumina catalyst

Tatiana Yuzhakova, A. Rédey, Endre Domokos, József Kovács, Monica Caldararu, Cristian Hornoiu, Mariana Carata, G. Postole, Cornel Munteanu, Larisa Strukova, Jozsef Fazakas

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Abstract

Molybdena-alumina (Mo/Al2O3) catalysts are widely used in the chemical and petrochemical industry because of their great importance in hydrogenation and hydrodesulfuration processes. Hydrogenation of heavy distillates can convert aromatics (benzene) into naphthenes (cyclohexane), which are cleaner-burning compounds and have less hazardous impact. Mildly reduced molybdena-alumina catalyst at 773 up to 973 K is suitable only for hydrogen-deuterium exchange of benzene, but for higher extent of catalyst reduction (at 1073-1173K) deuteration (hydrogenation) products of benzene can be observed. This research has been focused on the monitoring the surface active sites of Mo/Al2O3 catalyst after pretreatment in hydrogen at 773 and 1173 K by Fourier Transform Infrared (FTIR) spectroscopic method. Presence of Al3+ tet (IR band at 2234 cm-1), Mo5+(2205cm-1), Mo2+(2050cm-1), possibly Mo4+, Mo3+ together with Al3+ oct (broad peak at 2191cm-1) and Al-OH (2150cm-1) species was confirmed by low temperature (78K) adsorption of CO molecules after reduction of catalyst at 773K. Increasing the reduction temperature from 773 to 1173K diminishes Mo5+ and increases the population of Mo2+, Mo0 (2025 and 1991cm-1) species. The disappearance of the band corresponding to physically adsorbed CO (at 2150 cm-1) for the catalyst reduced at higher temperature supports the idea of occurrence of the dehydroxylation process. FTIR results are in agreement with the catalytic test, where the activity of catalyst for deuterium exchange of benzene decreases with increase extent of reduction of molybdena-alumina catalyst and with the extent of dehydroxylation of the catalyst.

Original languageEnglish
Pages (from-to)379-385
Number of pages7
JournalEnvironmental Engineering and Management Journal
Volume3
Issue number3
Publication statusPublished - Sep 1 2004

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Keywords

  • FTIR CO adsorption
  • Hydrotreating
  • Molybdena-alumina catalyst

ASJC Scopus subject areas

  • Environmental Engineering
  • Pollution
  • Management, Monitoring, Policy and Law

Cite this

Yuzhakova, T., Rédey, A., Domokos, E., Kovács, J., Caldararu, M., Hornoiu, C., Carata, M., Postole, G., Munteanu, C., Strukova, L., & Fazakas, J. (2004). Surface chemistry studies on molybdena-alumina catalyst. Environmental Engineering and Management Journal, 3(3), 379-385.