57Fe Mossbauer investigation of the substitutional effect of praseodymium in 1-2-3 compounds

E. Kuzmann, Z. Klencsár, Z. Homonnay, L. Pöppl, A. Vértes, M. Bódogh, I. Kotsis, A. Nath

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Abstract

57Fe Mossbauer spectroscopy measurements were performed on the perovskite compounds Eu0.7Pr0.3Ba2(Cu0.9957Fe0.01)3O(7-δ), EuBa1.5Pr0.5(Cu0.9957Fe0.01)3O(7-δ) and EuBa1.3Pr0.7(Cu0.9957Fe0.01)3O(7-δ). The observed 57Fe Mossbauer spectra provided an evidence for the correct site assignment of subspectra originating from 57Fe in different microenvironments. Apart from a minor component which was assigned to the 57Fe in the Cu(2) site of the copper oxide plane, all the subspectra could be attributed to the 57Fe in the Cu(1) copper oxide chain site with a fourfold (doublet D1), fivefold (doublet D2) or sixfold (doublet D3) oxygen coordination. In contrast, in the compound EuBa2(Cu0.9957Fe0.01)3O(7-δ) the 6-coordinated (D3) species has not been observed. The substitution of Pr for Eu or for Ba resulted in an increased occupancy of the O(5) antichain oxygen sites, which was explained by the charge neutrality criterion. Especially, the replacement of Ba2+ with Pr3+ led to an unusually high degree of occupancy of O(5) sites. In the 57Fe Mossbauer spectra the relative area of the 6-coordinated species (D3) increased, and that of the 4-coordinated one (D1) vanished completely in the case when Pr was substituted for Ba. Furthermore, the proportion of the 6-coordinated (D3) species increased at the expense of the 5-coordinated (D2) one with an increasing concentration of Pr at the Ba site. These experimental results are consistent with the variety of Mossbauer results reported so far.

Original languageEnglish
Pages (from-to)117-121
Number of pages5
JournalJournal of Radioanalytical and Nuclear Chemistry
Volume246
Issue number1
DOIs
Publication statusPublished - 2000

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Praseodymium
Copper oxides
Oxides
Copper
Mossbauer Spectroscopy
Oxygen
Mossbauer spectroscopy
Perovskite
Substitution reactions

ASJC Scopus subject areas

  • Analytical Chemistry
  • Inorganic Chemistry
  • Nuclear Energy and Engineering

Cite this

@article{accfaa3f06cc49f980fc42eaf65431f6,
title = "57Fe Mossbauer investigation of the substitutional effect of praseodymium in 1-2-3 compounds",
abstract = "57Fe Mossbauer spectroscopy measurements were performed on the perovskite compounds Eu0.7Pr0.3Ba2(Cu0.9957Fe0.01)3O(7-δ), EuBa1.5Pr0.5(Cu0.9957Fe0.01)3O(7-δ) and EuBa1.3Pr0.7(Cu0.9957Fe0.01)3O(7-δ). The observed 57Fe Mossbauer spectra provided an evidence for the correct site assignment of subspectra originating from 57Fe in different microenvironments. Apart from a minor component which was assigned to the 57Fe in the Cu(2) site of the copper oxide plane, all the subspectra could be attributed to the 57Fe in the Cu(1) copper oxide chain site with a fourfold (doublet D1), fivefold (doublet D2) or sixfold (doublet D3) oxygen coordination. In contrast, in the compound EuBa2(Cu0.9957Fe0.01)3O(7-δ) the 6-coordinated (D3) species has not been observed. The substitution of Pr for Eu or for Ba resulted in an increased occupancy of the O(5) antichain oxygen sites, which was explained by the charge neutrality criterion. Especially, the replacement of Ba2+ with Pr3+ led to an unusually high degree of occupancy of O(5) sites. In the 57Fe Mossbauer spectra the relative area of the 6-coordinated species (D3) increased, and that of the 4-coordinated one (D1) vanished completely in the case when Pr was substituted for Ba. Furthermore, the proportion of the 6-coordinated (D3) species increased at the expense of the 5-coordinated (D2) one with an increasing concentration of Pr at the Ba site. These experimental results are consistent with the variety of Mossbauer results reported so far.",
author = "E. Kuzmann and Z. Klencs{\'a}r and Z. Homonnay and L. P{\"o}ppl and A. V{\'e}rtes and M. B{\'o}dogh and I. Kotsis and A. Nath",
year = "2000",
doi = "10.1023/A:1006753719787",
language = "English",
volume = "246",
pages = "117--121",
journal = "Journal of Radioanalytical and Nuclear Chemistry",
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T1 - 57Fe Mossbauer investigation of the substitutional effect of praseodymium in 1-2-3 compounds

AU - Kuzmann, E.

AU - Klencsár, Z.

AU - Homonnay, Z.

AU - Pöppl, L.

AU - Vértes, A.

AU - Bódogh, M.

AU - Kotsis, I.

AU - Nath, A.

PY - 2000

Y1 - 2000

N2 - 57Fe Mossbauer spectroscopy measurements were performed on the perovskite compounds Eu0.7Pr0.3Ba2(Cu0.9957Fe0.01)3O(7-δ), EuBa1.5Pr0.5(Cu0.9957Fe0.01)3O(7-δ) and EuBa1.3Pr0.7(Cu0.9957Fe0.01)3O(7-δ). The observed 57Fe Mossbauer spectra provided an evidence for the correct site assignment of subspectra originating from 57Fe in different microenvironments. Apart from a minor component which was assigned to the 57Fe in the Cu(2) site of the copper oxide plane, all the subspectra could be attributed to the 57Fe in the Cu(1) copper oxide chain site with a fourfold (doublet D1), fivefold (doublet D2) or sixfold (doublet D3) oxygen coordination. In contrast, in the compound EuBa2(Cu0.9957Fe0.01)3O(7-δ) the 6-coordinated (D3) species has not been observed. The substitution of Pr for Eu or for Ba resulted in an increased occupancy of the O(5) antichain oxygen sites, which was explained by the charge neutrality criterion. Especially, the replacement of Ba2+ with Pr3+ led to an unusually high degree of occupancy of O(5) sites. In the 57Fe Mossbauer spectra the relative area of the 6-coordinated species (D3) increased, and that of the 4-coordinated one (D1) vanished completely in the case when Pr was substituted for Ba. Furthermore, the proportion of the 6-coordinated (D3) species increased at the expense of the 5-coordinated (D2) one with an increasing concentration of Pr at the Ba site. These experimental results are consistent with the variety of Mossbauer results reported so far.

AB - 57Fe Mossbauer spectroscopy measurements were performed on the perovskite compounds Eu0.7Pr0.3Ba2(Cu0.9957Fe0.01)3O(7-δ), EuBa1.5Pr0.5(Cu0.9957Fe0.01)3O(7-δ) and EuBa1.3Pr0.7(Cu0.9957Fe0.01)3O(7-δ). The observed 57Fe Mossbauer spectra provided an evidence for the correct site assignment of subspectra originating from 57Fe in different microenvironments. Apart from a minor component which was assigned to the 57Fe in the Cu(2) site of the copper oxide plane, all the subspectra could be attributed to the 57Fe in the Cu(1) copper oxide chain site with a fourfold (doublet D1), fivefold (doublet D2) or sixfold (doublet D3) oxygen coordination. In contrast, in the compound EuBa2(Cu0.9957Fe0.01)3O(7-δ) the 6-coordinated (D3) species has not been observed. The substitution of Pr for Eu or for Ba resulted in an increased occupancy of the O(5) antichain oxygen sites, which was explained by the charge neutrality criterion. Especially, the replacement of Ba2+ with Pr3+ led to an unusually high degree of occupancy of O(5) sites. In the 57Fe Mossbauer spectra the relative area of the 6-coordinated species (D3) increased, and that of the 4-coordinated one (D1) vanished completely in the case when Pr was substituted for Ba. Furthermore, the proportion of the 6-coordinated (D3) species increased at the expense of the 5-coordinated (D2) one with an increasing concentration of Pr at the Ba site. These experimental results are consistent with the variety of Mossbauer results reported so far.

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