Study on Ferrocenes, Part 7. E-2-Ferrocenemethylene-1-benzocyclanones. Synthesis, stereostructure, NMR, IR X-ray, and Mossbauer spectroscopic investigation

P. Sohár, P. Perjési, K. W. Törnroos, S. Husebye, A. Vértes, Gy Vankó, R. E. Bozak

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

A series of E-2-ferrocenemethylene-1-benzocyclanones (3a-e) were synthesized by base-catalysed condensation of ferrocenecarboxaldehyde (2) with benzocyclanones 1a-e. The stereostructure (configuration and conformation) and the electronic properties (conjugation of the enone moiety with the aromatic rings) of the compounds were studied by IR, 1H and 13C NMR and Mossbauer spectroscopy. The structure of E-2-ferrocenemethylene-1- benzosuberone (3c) was also investigated by X-ray spectroscopy. (C) 2000 Elsevier Science B.V.

Original languageEnglish
Pages (from-to)297-304
Number of pages8
JournalJournal of Molecular Structure
Volume524
Issue number1-3
DOIs
Publication statusPublished - Jun 13 2000

Keywords

  • Base-catalysed condensation
  • Ferrocenes
  • IR and Mossbauer spectroscopic and X-ray investigation
  • NMR

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy
  • Organic Chemistry
  • Inorganic Chemistry

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