Study of the absorption characteristics of a zeolite support in normal and reversed-phase thin-layer chromatography

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2 Citations (Scopus)

Abstract

The retention behavior of 36 synthetic dyes has been studied in adsorption and reversed-phase TLC on zeolite layers with n-hexane, tetrahydrofuran, and bidistilled water as mobile phases. Linear regression analysis (LRA) was used to compare the retention of the dyes when different mobile phases were used. The relationship between retention and the lipophilicity and specific hydrophobic surface area of the analytes was elucidated by stepwise regression analysis (SRA). Significant linear correlations were found between the retention of the dyes chromatographed with the different mobile phases, proving the regular retention behavior of the analytes. No linear relationship was found between the physicochemical properties of the dyes and their retention, suggesting the separation capacity of zeolite differs markedly from that of silica and silica coated with hydrophobic ligands.

Original languageEnglish
Pages (from-to)381-384
Number of pages4
JournalJournal of Planar Chromatography - Modern TLC
Volume20
Issue number5
DOIs
Publication statusPublished - Oct 2007

Fingerprint

Zeolites
Thin layer chromatography
Reverse-Phase Chromatography
Thin Layer Chromatography
Coloring Agents
Regression analysis
Silicon Dioxide
Regression Analysis
Linear regression
Adsorption
Linear Models
Ligands
Water

Keywords

  • Adsorption and reversed-phase TLC
  • Adsorption strength
  • Synthetic dyes
  • Zeolite stationary phase

ASJC Scopus subject areas

  • Analytical Chemistry

Cite this

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abstract = "The retention behavior of 36 synthetic dyes has been studied in adsorption and reversed-phase TLC on zeolite layers with n-hexane, tetrahydrofuran, and bidistilled water as mobile phases. Linear regression analysis (LRA) was used to compare the retention of the dyes when different mobile phases were used. The relationship between retention and the lipophilicity and specific hydrophobic surface area of the analytes was elucidated by stepwise regression analysis (SRA). Significant linear correlations were found between the retention of the dyes chromatographed with the different mobile phases, proving the regular retention behavior of the analytes. No linear relationship was found between the physicochemical properties of the dyes and their retention, suggesting the separation capacity of zeolite differs markedly from that of silica and silica coated with hydrophobic ligands.",
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AB - The retention behavior of 36 synthetic dyes has been studied in adsorption and reversed-phase TLC on zeolite layers with n-hexane, tetrahydrofuran, and bidistilled water as mobile phases. Linear regression analysis (LRA) was used to compare the retention of the dyes when different mobile phases were used. The relationship between retention and the lipophilicity and specific hydrophobic surface area of the analytes was elucidated by stepwise regression analysis (SRA). Significant linear correlations were found between the retention of the dyes chromatographed with the different mobile phases, proving the regular retention behavior of the analytes. No linear relationship was found between the physicochemical properties of the dyes and their retention, suggesting the separation capacity of zeolite differs markedly from that of silica and silica coated with hydrophobic ligands.

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