Polielektrolitok és ionos tenzidek kölcsönhatá sának vizsgálata

Translated title of the contribution: Study of electrolyte - Ionic surfactant interactions

S. Bárány, Imre Bader, Tatyana Pakhar

Research output: Contribution to journalArticle

Abstract

Using viscosity, electrical conductivity, light transmittance and electrophoreses methods, the interactions between cationic/anionic polyelectrolytes of different charge density and molecular mass and ionic surfactants in aqueous and electrolyte solutions have been studied. Strong interactions between components are observed due to electrostatic attraction between oppositely charged polymers and surfactants, which are manifested by a substantial reduction of solution viscosity and light transmittance as well as by a relative decease in conductivity of the systems. With increasing the surfactant content, the formed PE-tenside complexes precipitate and then dissolve again. For highly charged polyelectrolytes a wide destabilization zone is observed and at high surfactant concentrations only partial dissolution of insoluble complexes takes place. In this region the ratio between charges of surfactant and polyelectrolyte reaches 3-4. With increasing the C atom numbers in the SAA molecule, the concentration of the surfactant at which reduction in system viscosity and light transmittance occurs diminishes. This is an evidence of the important role of hydrophobic interactions in binding and cooperation between adsorbed surfactant molecules. As a result of operation of these forces also interactions between high molecular anionic polyelectrolytes and anionic surfactants take place.

Original languageHungarian
Pages (from-to)215-220
Number of pages6
JournalMagyar Kemiai Folyoirat, Kemiai Kozlemenyek
Volume108
Issue number5
Publication statusPublished - May 2002

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Surface-Active Agents
Electrolytes
Polyelectrolytes
Viscosity
Molecules
Anionic surfactants
Molecular mass
Charge density
Precipitates
Electrostatics
Polymers
Dissolution
Atoms

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Polielektrolitok és ionos tenzidek kölcsönhatá sának vizsgálata. / Bárány, S.; Bader, Imre; Pakhar, Tatyana.

In: Magyar Kemiai Folyoirat, Kemiai Kozlemenyek, Vol. 108, No. 5, 05.2002, p. 215-220.

Research output: Contribution to journalArticle

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