Studies on the chemistry of diols and cyclic ethers-53. Dehydration of 1,1-bishydroxymethylcycloalkanes

a quest for a 1,3-hydride shift

Árpád Molnár, I. Bucsi, M. Bartók

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

A study of the sulphuric acid-catalysed dehydrations of 1,1-bishydroxymethyl-cyclopropane, -cyclobutane, - cyclopentane and -cyclohexane (1a-1d) revealed that the product distributions are determined by the relative stabilities of carbenium ions and der kinetic control furnished evidence of a 1,3-hydride shift.

Original languageEnglish
Pages (from-to)4929-4936
Number of pages8
JournalTetrahedron
Volume48
Issue number23
DOIs
Publication statusPublished - Jun 5 1992

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Cyclic Ethers
Cyclobutanes
Cyclopentanes
Dehydration
Hydrides
Ions
Kinetics
Acids
cyclopropane
Cyclohexane

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Studies on the chemistry of diols and cyclic ethers-53. Dehydration of 1,1-bishydroxymethylcycloalkanes : a quest for a 1,3-hydride shift. / Molnár, Árpád; Bucsi, I.; Bartók, M.

In: Tetrahedron, Vol. 48, No. 23, 05.06.1992, p. 4929-4936.

Research output: Contribution to journalArticle

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