Structure determination of zinc complexes of iminodiacetamide ionophores in solution and in the solid state

Gábor Tóth, B. Balázs, Gyula Horváth, Damian Magiera, Helmut Duddeck, I. Bitter

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

It is shown by extensive NMR investigation that hexa-coordinated Zn 2+-complexes containing two tridentate iminodiacetamide ligands adopt a solution conformation with two different kinds of Zn-O bonds possessing a center of inversion. In contrast, the complex molecules are chiral in the solid state as determined by CP-MAS 13C NMR spectroscopy.

Original languageEnglish
Pages (from-to)145-148
Number of pages4
JournalJournal of Inclusion Phenomena
Volume43
Issue number1-2
DOIs
Publication statusPublished - 2002

Fingerprint

Ionophores
ionophores
Nuclear magnetic resonance spectroscopy
Conformations
nuclear magnetic resonance spectroscopy
Zinc
Magnetic Resonance Spectroscopy
zinc
Nuclear magnetic resonance
Ligands
solid state
nuclear magnetic resonance
Molecules
inversions
ligands
spectroscopy
molecules
Carbon-13 Magnetic Resonance Spectroscopy

Keywords

  • Iminodiacetamides
  • Liquid-state and solid-state structures
  • NMR spectroscopy
  • Zinc

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics

Cite this

Structure determination of zinc complexes of iminodiacetamide ionophores in solution and in the solid state. / Tóth, Gábor; Balázs, B.; Horváth, Gyula; Magiera, Damian; Duddeck, Helmut; Bitter, I.

In: Journal of Inclusion Phenomena, Vol. 43, No. 1-2, 2002, p. 145-148.

Research output: Contribution to journalArticle

Tóth, Gábor ; Balázs, B. ; Horváth, Gyula ; Magiera, Damian ; Duddeck, Helmut ; Bitter, I. / Structure determination of zinc complexes of iminodiacetamide ionophores in solution and in the solid state. In: Journal of Inclusion Phenomena. 2002 ; Vol. 43, No. 1-2. pp. 145-148.
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