Structure determination of an unusual [2.2]paracyclophane derivative by NMR spectroscopy

E. Gács-Baitz, O. Egyed, Aldo Taticchi, Lucio Minuti, Assunta Marrocchi

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Our ongoing study on cycloaddition reactions of dienes with different dienophiles afforded a great variety of derivatives with interesting molecular structures and electronic behavior. A new type of angularly annelated [2.2]paracyclophane (3) has been synthesize by the Diels-Alder reaction of 4-(2-propenyl[2.2]paracyclophane (1) and 1,4-benzoquinone (2) under high pressure conditions. The structure determination of this compound has been achieved by NMR measurements and semiempirical calculations.

Original languageEnglish
Pages (from-to)581-585
Number of pages5
JournalStructural Chemistry
Volume16
Issue number6
DOIs
Publication statusPublished - Dec 2005

Fingerprint

Cycloaddition Reaction
Nuclear magnetic resonance spectroscopy
Magnetic Resonance Spectroscopy
Derivatives
Molecular electronics
Diels-Alder reactions
nuclear magnetic resonance
Cycloaddition
molecular electronics
cycloaddition
quinones
dienes
Molecular Structure
Molecular structure
spectroscopy
molecular structure
Nuclear magnetic resonance
Pressure
(2.2)paracyclophane
benzoquinone

Keywords

  • H and C NMR spectroscopy
  • Cyclophanes
  • Molecular structure
  • Semiempirical calculations

ASJC Scopus subject areas

  • Chemistry(all)
  • Structural Biology

Cite this

Structure determination of an unusual [2.2]paracyclophane derivative by NMR spectroscopy. / Gács-Baitz, E.; Egyed, O.; Taticchi, Aldo; Minuti, Lucio; Marrocchi, Assunta.

In: Structural Chemistry, Vol. 16, No. 6, 12.2005, p. 581-585.

Research output: Contribution to journalArticle

Gács-Baitz, E. ; Egyed, O. ; Taticchi, Aldo ; Minuti, Lucio ; Marrocchi, Assunta. / Structure determination of an unusual [2.2]paracyclophane derivative by NMR spectroscopy. In: Structural Chemistry. 2005 ; Vol. 16, No. 6. pp. 581-585.
@article{4371c91d8b824ccbb2b35958434804f8,
title = "Structure determination of an unusual [2.2]paracyclophane derivative by NMR spectroscopy",
abstract = "Our ongoing study on cycloaddition reactions of dienes with different dienophiles afforded a great variety of derivatives with interesting molecular structures and electronic behavior. A new type of angularly annelated [2.2]paracyclophane (3) has been synthesize by the Diels-Alder reaction of 4-(2-propenyl[2.2]paracyclophane (1) and 1,4-benzoquinone (2) under high pressure conditions. The structure determination of this compound has been achieved by NMR measurements and semiempirical calculations.",
keywords = "H and C NMR spectroscopy, Cyclophanes, Molecular structure, Semiempirical calculations",
author = "E. G{\'a}cs-Baitz and O. Egyed and Aldo Taticchi and Lucio Minuti and Assunta Marrocchi",
year = "2005",
month = "12",
doi = "10.1007/s11224-005-6098-1",
language = "English",
volume = "16",
pages = "581--585",
journal = "Structural Chemistry",
issn = "1040-0400",
publisher = "Springer New York",
number = "6",

}

TY - JOUR

T1 - Structure determination of an unusual [2.2]paracyclophane derivative by NMR spectroscopy

AU - Gács-Baitz, E.

AU - Egyed, O.

AU - Taticchi, Aldo

AU - Minuti, Lucio

AU - Marrocchi, Assunta

PY - 2005/12

Y1 - 2005/12

N2 - Our ongoing study on cycloaddition reactions of dienes with different dienophiles afforded a great variety of derivatives with interesting molecular structures and electronic behavior. A new type of angularly annelated [2.2]paracyclophane (3) has been synthesize by the Diels-Alder reaction of 4-(2-propenyl[2.2]paracyclophane (1) and 1,4-benzoquinone (2) under high pressure conditions. The structure determination of this compound has been achieved by NMR measurements and semiempirical calculations.

AB - Our ongoing study on cycloaddition reactions of dienes with different dienophiles afforded a great variety of derivatives with interesting molecular structures and electronic behavior. A new type of angularly annelated [2.2]paracyclophane (3) has been synthesize by the Diels-Alder reaction of 4-(2-propenyl[2.2]paracyclophane (1) and 1,4-benzoquinone (2) under high pressure conditions. The structure determination of this compound has been achieved by NMR measurements and semiempirical calculations.

KW - H and C NMR spectroscopy

KW - Cyclophanes

KW - Molecular structure

KW - Semiempirical calculations

UR - http://www.scopus.com/inward/record.url?scp=29244451067&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=29244451067&partnerID=8YFLogxK

U2 - 10.1007/s11224-005-6098-1

DO - 10.1007/s11224-005-6098-1

M3 - Article

AN - SCOPUS:29244451067

VL - 16

SP - 581

EP - 585

JO - Structural Chemistry

JF - Structural Chemistry

SN - 1040-0400

IS - 6

ER -