Structural studies on optical resolution via diasteroisomeric salt formation. Enantiomer separation for cis-permethrinic acid [cis-2,2-dimethyl-3- (2,2-dichlorovinyl)cyclopropanecarboxylic acid]

E. Fogassy, F. Faigl, Mária Ács, Kálmán Simon, Éva Kozsda, Benjámin Podányi, M. Czugler, Günther Reck

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18 Citations (Scopus)

Abstract

The pH dependence of enantiomer separation by optical resolution of cis-2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropanecarboxylic acid (I) with (S)-2-benzylaminobutanol (II) has been investigated. Thermodynamic constants, thermal behaviour, and the molecular and crystal structure were determined in order to evaluate and interpret the results of optical resolution.

Original languageEnglish
Pages (from-to)1385-1392
Number of pages8
JournalJournal of the Chemical Society, Perkin Transactions 2
Issue number8
DOIs
Publication statusPublished - 1988

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NSC 153174
Enantiomers
Molecular structure
Salts
Crystal structure
Thermodynamics
cyclopropanecarboxylic acid
Hot Temperature

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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title = "Structural studies on optical resolution via diasteroisomeric salt formation. Enantiomer separation for cis-permethrinic acid [cis-2,2-dimethyl-3- (2,2-dichlorovinyl)cyclopropanecarboxylic acid]",
abstract = "The pH dependence of enantiomer separation by optical resolution of cis-2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropanecarboxylic acid (I) with (S)-2-benzylaminobutanol (II) has been investigated. Thermodynamic constants, thermal behaviour, and the molecular and crystal structure were determined in order to evaluate and interpret the results of optical resolution.",
author = "E. Fogassy and F. Faigl and M{\'a}ria {\'A}cs and K{\'a}lm{\'a}n Simon and {\'E}va Kozsda and Benj{\'a}min Pod{\'a}nyi and M. Czugler and G{\"u}nther Reck",
year = "1988",
doi = "10.1039/P29880001385",
language = "English",
pages = "1385--1392",
journal = "Journal of the Chemical Society, Perkin Transactions 2",
issn = "1470-1820",
publisher = "Royal Society of Chemistry",
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TY - JOUR

T1 - Structural studies on optical resolution via diasteroisomeric salt formation. Enantiomer separation for cis-permethrinic acid [cis-2,2-dimethyl-3- (2,2-dichlorovinyl)cyclopropanecarboxylic acid]

AU - Fogassy, E.

AU - Faigl, F.

AU - Ács, Mária

AU - Simon, Kálmán

AU - Kozsda, Éva

AU - Podányi, Benjámin

AU - Czugler, M.

AU - Reck, Günther

PY - 1988

Y1 - 1988

N2 - The pH dependence of enantiomer separation by optical resolution of cis-2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropanecarboxylic acid (I) with (S)-2-benzylaminobutanol (II) has been investigated. Thermodynamic constants, thermal behaviour, and the molecular and crystal structure were determined in order to evaluate and interpret the results of optical resolution.

AB - The pH dependence of enantiomer separation by optical resolution of cis-2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropanecarboxylic acid (I) with (S)-2-benzylaminobutanol (II) has been investigated. Thermodynamic constants, thermal behaviour, and the molecular and crystal structure were determined in order to evaluate and interpret the results of optical resolution.

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U2 - 10.1039/P29880001385

DO - 10.1039/P29880001385

M3 - Article

SP - 1385

EP - 1392

JO - Journal of the Chemical Society, Perkin Transactions 2

JF - Journal of the Chemical Society, Perkin Transactions 2

SN - 1470-1820

IS - 8

ER -