Structural investigation of dibenzyltin(IV) complexes of carbohydrates

N. Buzás, M. A. Pujar, L. Nagy, A. Vértes, E. Kuzmann, H. Mehner

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Dibenzyltin(IV) complexes of carbohydrate derivatives were prepared and studied by Mössbauer and FTIR spectroscopy and by thermogravimetry. The Mössbauer studies indicated that the reaction between dibenzyltin(IV)-dichloride and sugar-type ligands led to reaction products containing tin(IV)-oxide. beside the dibenzyltin(IV) sugar complex. These two type of species were shown to be in weak interaction. Comparison of the experimental quadrupole splitting values with those calculated on the basis of the partial quadrupole splitting concept revealed the steric arrangements of the coordination sphere of tin(IV) in the sugar complexes.

Original languageEnglish
Pages (from-to)237-245
Number of pages9
JournalJournal of Radioanalytical and Nuclear Chemistry Articles
Volume189
Issue number2
DOIs
Publication statusPublished - Jan 1 1995

ASJC Scopus subject areas

  • Analytical Chemistry
  • Nuclear Energy and Engineering
  • Radiology Nuclear Medicine and imaging
  • Pollution
  • Spectroscopy
  • Public Health, Environmental and Occupational Health
  • Health, Toxicology and Mutagenesis

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