Structural Aspects of Fe3O4/CoFe2O4 Magnetic Nanoparticles According to X-Ray and Neutron Scattering

A. V. Nagornyi, M. V. Avdeev, O. V. Yelenich, S. O. Solopan, A. G. Belous, A. V. Shulenina, V. A. Turchenko, D. V. Soloviov, L. A. Bulavin, V. Aksenov

Research output: Contribution to journalArticle

Abstract

Structural aspects of powders containing magnetic nanoparticles Fe3O4/CoFe2O4 with the anticipated “core-shell” structure are considered by means of comparative analysis with individual particles of Fe3O4, CoFe2O4 in accordance of data obtained from X-ray powder diffraction and small-angle scattering of X-ray (synchrotron) radiation and neutrons. It is shown that magnetic particles in the powders under study have a strong polydispersity and form complex aggregates. Characteristic sizes of the crystallites, as well as a ratio of magnetite to cobalt-ferrite in the composition of the Fe3O4/CoFe2O4 particles were evaluated from the analysis of the diffraction peaks. Аnalyzing the data on small-angle scattering, the dimensional characteristics of particles and aggregates, as well as the volume fraction of the last ones in the powders, have been obtained. Fractal dimensions of aggregates are determined. A significant difference is observed in the scattering on Fe3O4/CoFe2O4 particles and the total scattering consisting of partial contributions to scattering on individual magnetite (Fe3O4) and cobalt-ferrite (CoFe2O4) powders, which does not exclude the formation of the “core-shell” structure.

Original languageEnglish
Pages (from-to)737-743
Number of pages7
JournalJournal of Surface Investigation
Volume12
Issue number4
DOIs
Publication statusPublished - Jul 1 2018

Fingerprint

Neutron scattering
X ray scattering
Scattering
Nanoparticles
Powders
Magnetite
Ferrosoferric Oxide
Ferrite
Cobalt
Polydispersity
Fractal dimension
Synchrotron radiation
Crystallites
X ray powder diffraction
Volume fraction
Neutrons
Diffraction
cobalt ferrite
X rays
Chemical analysis

Keywords

  • magnetic nanoparticles
  • powder diffraction
  • small-angle neutron scattering
  • small-angle X-ray (synchrotron) scattering
  • “core–shell” structure

ASJC Scopus subject areas

  • Surfaces, Coatings and Films

Cite this

Structural Aspects of Fe3O4/CoFe2O4 Magnetic Nanoparticles According to X-Ray and Neutron Scattering. / Nagornyi, A. V.; Avdeev, M. V.; Yelenich, O. V.; Solopan, S. O.; Belous, A. G.; Shulenina, A. V.; Turchenko, V. A.; Soloviov, D. V.; Bulavin, L. A.; Aksenov, V.

In: Journal of Surface Investigation, Vol. 12, No. 4, 01.07.2018, p. 737-743.

Research output: Contribution to journalArticle

Nagornyi, AV, Avdeev, MV, Yelenich, OV, Solopan, SO, Belous, AG, Shulenina, AV, Turchenko, VA, Soloviov, DV, Bulavin, LA & Aksenov, V 2018, 'Structural Aspects of Fe3O4/CoFe2O4 Magnetic Nanoparticles According to X-Ray and Neutron Scattering', Journal of Surface Investigation, vol. 12, no. 4, pp. 737-743. https://doi.org/10.1134/S102745101804033X
Nagornyi, A. V. ; Avdeev, M. V. ; Yelenich, O. V. ; Solopan, S. O. ; Belous, A. G. ; Shulenina, A. V. ; Turchenko, V. A. ; Soloviov, D. V. ; Bulavin, L. A. ; Aksenov, V. / Structural Aspects of Fe3O4/CoFe2O4 Magnetic Nanoparticles According to X-Ray and Neutron Scattering. In: Journal of Surface Investigation. 2018 ; Vol. 12, No. 4. pp. 737-743.
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