Strategies toward phosphorus-containing PAHs and the effect of P-substitution on the electronic properties

Rózsa Szucs, François Riobé, Aude Escande, Damien Joly, Pierre Antoine Bouit, L. Nyulászi, Muriel Hissler

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

In this paper, we report on the different synthetic strategies which led to the preparation of a whole family of polyaromatic hydrocarbons containing a P-Atom at the edge. In particular, we show from both experimental and theoretical perspective how the Scholl method has to be adapted to the specificity of organophosphorus derivatives. The P-modified PAHs possess the classical phosphane reactivity that allows fine-Tuning of their electronic properties as evidenced by spectro-electrochemistry and theoretical calculations. In particular, the effect of P-substitution on the aromaticity of the different cycles of the PAH was studied.

Original languageEnglish
Pages (from-to)341-355
Number of pages15
JournalPure and Applied Chemistry
Volume89
Issue number3
DOIs
Publication statusPublished - Mar 1 2017

Fingerprint

phosphine
Polycyclic aromatic hydrocarbons
Electronic properties
Phosphorus
Substitution reactions
Spectroelectrochemistry
Hydrocarbons
Tuning
Derivatives
Atoms

Keywords

  • aromaticity
  • ICPC-21
  • organophosphorus chemistry
  • phosphole
  • polyaromatics
  • spectro-electrochemistry

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Strategies toward phosphorus-containing PAHs and the effect of P-substitution on the electronic properties. / Szucs, Rózsa; Riobé, François; Escande, Aude; Joly, Damien; Bouit, Pierre Antoine; Nyulászi, L.; Hissler, Muriel.

In: Pure and Applied Chemistry, Vol. 89, No. 3, 01.03.2017, p. 341-355.

Research output: Contribution to journalArticle

Szucs, Rózsa ; Riobé, François ; Escande, Aude ; Joly, Damien ; Bouit, Pierre Antoine ; Nyulászi, L. ; Hissler, Muriel. / Strategies toward phosphorus-containing PAHs and the effect of P-substitution on the electronic properties. In: Pure and Applied Chemistry. 2017 ; Vol. 89, No. 3. pp. 341-355.
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