Steric hindrance in the synthesis and properties of the dimer of 1-(2,4,6-tri-tert-butylphenyl)phosphole 1-oxide

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Abstract

Steric hindrance was observed during the oxidation of 2,4,6-tri-tert-butylphenylphosphole to the P oxide and in the dimerization of this latter species to the corresponding phosphanorbornene derivative. Single-crystal X-ray analysis of the dimer revealed considerable steric crowding around the P atoms. Deoxygenation of the dimer of the phosphole oxide by Cl3SiH-C6H5N could only be accomplished under forcing conditions at 110°C.

Original languageEnglish
Pages (from-to)527-531
Number of pages5
JournalHeteroatom Chemistry
Volume8
Issue number6
DOIs
Publication statusPublished - Jan 1 1997

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ASJC Scopus subject areas

  • Chemistry(all)

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