Steric control and the mechanism of benzaldehyde oxidation by polypyridyl oxoiron(IV) complexes: Aromatic: versus benzylic hydroxylation of aromatic aldehydes

Ramona Turcas, Dóra Lakk-Bogáth, G. Speier, J. Kaizer

Research output: Contribution to journalReview article

8 Citations (Scopus)

Abstract

The present study describes the first example of the hydroxylation of benzaldehydes by synthetic nonheme oxoiron(iv) complexes, where the reactivity, chemoselectivity, and mechanism were strongly influenced by the ligand environment of the iron center.

Original languageEnglish
Pages (from-to)3248-3252
Number of pages5
JournalDalton Transactions
Volume47
Issue number10
DOIs
Publication statusPublished - Jan 1 2018

Fingerprint

Benzaldehydes
Hydroxylation
Aldehydes
Iron
Ligands
Oxidation
benzaldehyde

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Steric control and the mechanism of benzaldehyde oxidation by polypyridyl oxoiron(IV) complexes : Aromatic: versus benzylic hydroxylation of aromatic aldehydes. / Turcas, Ramona; Lakk-Bogáth, Dóra; Speier, G.; Kaizer, J.

In: Dalton Transactions, Vol. 47, No. 10, 01.01.2018, p. 3248-3252.

Research output: Contribution to journalReview article

@article{42594e126c9d4708b35ac1a1579df3b7,
title = "Steric control and the mechanism of benzaldehyde oxidation by polypyridyl oxoiron(IV) complexes: Aromatic: versus benzylic hydroxylation of aromatic aldehydes",
abstract = "The present study describes the first example of the hydroxylation of benzaldehydes by synthetic nonheme oxoiron(iv) complexes, where the reactivity, chemoselectivity, and mechanism were strongly influenced by the ligand environment of the iron center.",
author = "Ramona Turcas and D{\'o}ra Lakk-Bog{\'a}th and G. Speier and J. Kaizer",
year = "2018",
month = "1",
day = "1",
doi = "10.1039/c7dt03727a",
language = "English",
volume = "47",
pages = "3248--3252",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "10",

}

TY - JOUR

T1 - Steric control and the mechanism of benzaldehyde oxidation by polypyridyl oxoiron(IV) complexes

T2 - Aromatic: versus benzylic hydroxylation of aromatic aldehydes

AU - Turcas, Ramona

AU - Lakk-Bogáth, Dóra

AU - Speier, G.

AU - Kaizer, J.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - The present study describes the first example of the hydroxylation of benzaldehydes by synthetic nonheme oxoiron(iv) complexes, where the reactivity, chemoselectivity, and mechanism were strongly influenced by the ligand environment of the iron center.

AB - The present study describes the first example of the hydroxylation of benzaldehydes by synthetic nonheme oxoiron(iv) complexes, where the reactivity, chemoselectivity, and mechanism were strongly influenced by the ligand environment of the iron center.

UR - http://www.scopus.com/inward/record.url?scp=85043350766&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85043350766&partnerID=8YFLogxK

U2 - 10.1039/c7dt03727a

DO - 10.1039/c7dt03727a

M3 - Review article

AN - SCOPUS:85043350766

VL - 47

SP - 3248

EP - 3252

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 10

ER -