Stereoselective approach to some novel 16-methylated and 16-halomethylated tetrahydropyran and δ-lactone derivatives in both the normal and the 13α-estrone series

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11 Citations (Scopus)

Abstract

Intramolecular cyclizations of the 3-methyl ether of an unsaturated D-secoestrone alcohol and secoestrone carboxylic acid in both the normal and the 13α-estrone series are reported. The ring-closure reactions furnished substituted, new oxa-D-homoestrone derivatives stereoselectively.

Original languageEnglish
Pages (from-to)1803-1806
Number of pages4
JournalSynlett
Issue number11
Publication statusPublished - 2002

Fingerprint

Methyl Ethers
Estrone
Cyclization
Lactones
Carboxylic Acids
Alcohols
Derivatives
D-homoestrone

Keywords

  • Cyclizations
  • Diastereoselectivity
  • Esterification
  • Estrone derivatives
  • Etherification

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

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abstract = "Intramolecular cyclizations of the 3-methyl ether of an unsaturated D-secoestrone alcohol and secoestrone carboxylic acid in both the normal and the 13α-estrone series are reported. The ring-closure reactions furnished substituted, new oxa-D-homoestrone derivatives stereoselectively.",
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journal = "Synlett",
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T1 - Stereoselective approach to some novel 16-methylated and 16-halomethylated tetrahydropyran and δ-lactone derivatives in both the normal and the 13α-estrone series

AU - Frank, E.

AU - Mernyák, E.

AU - Wölfling, J.

AU - Schneider, G.

PY - 2002

Y1 - 2002

N2 - Intramolecular cyclizations of the 3-methyl ether of an unsaturated D-secoestrone alcohol and secoestrone carboxylic acid in both the normal and the 13α-estrone series are reported. The ring-closure reactions furnished substituted, new oxa-D-homoestrone derivatives stereoselectively.

AB - Intramolecular cyclizations of the 3-methyl ether of an unsaturated D-secoestrone alcohol and secoestrone carboxylic acid in both the normal and the 13α-estrone series are reported. The ring-closure reactions furnished substituted, new oxa-D-homoestrone derivatives stereoselectively.

KW - Cyclizations

KW - Diastereoselectivity

KW - Esterification

KW - Estrone derivatives

KW - Etherification

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