Stereochemical studies, 47, saturated heterocycles, 25 a simple stereospecific synthesis of oxazasteroids

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Abstract

8-Aza-12-oxasteroids have been synthesized in a simple three-step process. As a consequence of two stareocontrolled reactions, the product is a stereospecifically homogeneous isomer with all-trans ring junctions; its structure has been determined by 1H and 13C NMR spectroscopy and X-ray diffraction.

Original languageEnglish
Pages (from-to)3797-3800
Number of pages4
JournalTetrahedron Letters
Volume22
Issue number38
DOIs
Publication statusPublished - 1981

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X-Ray Diffraction
Isomers
Nuclear magnetic resonance spectroscopy
Magnetic Resonance Spectroscopy
X ray diffraction
Carbon-13 Magnetic Resonance Spectroscopy
Proton Magnetic Resonance Spectroscopy

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

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title = "Stereochemical studies, 47, saturated heterocycles, 25 a simple stereospecific synthesis of oxazasteroids",
abstract = "8-Aza-12-oxasteroids have been synthesized in a simple three-step process. As a consequence of two stareocontrolled reactions, the product is a stereospecifically homogeneous isomer with all-trans ring junctions; its structure has been determined by 1H and 13C NMR spectroscopy and X-ray diffraction.",
author = "G. Bern{\'a}th and Perenc F{\"u}l{\"o}p and G. Argay and A. K{\'a}lm{\'a}n and P. Soh{\'a}r",
year = "1981",
doi = "10.1016/S0040-4039(01)82024-4",
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pages = "3797--3800",
journal = "Tetrahedron Letters",
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T1 - Stereochemical studies, 47, saturated heterocycles, 25 a simple stereospecific synthesis of oxazasteroids

AU - Bernáth, G.

AU - Fülöp, Perenc

AU - Argay, G.

AU - Kálmán, A.

AU - Sohár, P.

PY - 1981

Y1 - 1981

N2 - 8-Aza-12-oxasteroids have been synthesized in a simple three-step process. As a consequence of two stareocontrolled reactions, the product is a stereospecifically homogeneous isomer with all-trans ring junctions; its structure has been determined by 1H and 13C NMR spectroscopy and X-ray diffraction.

AB - 8-Aza-12-oxasteroids have been synthesized in a simple three-step process. As a consequence of two stareocontrolled reactions, the product is a stereospecifically homogeneous isomer with all-trans ring junctions; its structure has been determined by 1H and 13C NMR spectroscopy and X-ray diffraction.

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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