Spin trapping reactions with nitric oxides. V. Reactions with unsaturated macromolecular chains - a new spin labeling method

Miklós Gyor, Antal Rockenbauer, Ferenc Tüdos

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Abstract

Formation of macromolecular nitroxides (i.e., spin labeled polymer chains) has been detected by Electron Spin Resonance spectroscopy in the reaction of nitric oxide gas with several unsaturated polymers/synthetic polyisoprene, polybutadiene, poly(isoprene-co-isobutylene), poly(butadiene-co-styrene)/dissolved in aromatic hydrocarbons. Spectroscopic evidences of gel formation, precipitation, and of solvent effect have been given.

Original languageEnglish
Pages (from-to)4795-4798
Number of pages4
JournalTetrahedron Letters
Volume27
Issue number39
DOIs
Publication statusPublished - 1986

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ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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