Spin trapping reactions with nitric oxides IV. Reactions with olefins

Antal Rockenbauer, Miklós Gyor, Ferenc Tüdos

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Electron Spin Resonance spectra of nitroxide radicals formed in the nitrogen oxide olefin systems (isobutylene, styrene and α-methylstyrene) have been investigated. The primary reaction step is the formation of alkyl radicals by the addition of nitrogen dioxide to the methylene carbon of olefins. The nitric oxide scavenges two alkyl radicals. In styrene and α-methylstyrene nitroxide diastereomers with different rates of formation and termination have been observed.

Original languageEnglish
Pages (from-to)3425-3428
Number of pages4
JournalTetrahedron Letters
Volume27
Issue number29
DOIs
Publication statusPublished - 1986

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Fingerprint Dive into the research topics of 'Spin trapping reactions with nitric oxides IV. Reactions with olefins'. Together they form a unique fingerprint.

  • Cite this