Iron(III) complexes of D-saccharose and D-glucose were prepared. The compositions of the complexes were determined by standard analytical methods. The Mossbauer spectra reflected the presence of high-spin iron(III) in the polynuclear species. EPR spectroscopy demonstrated antiferromagnetically coupled iron(III) centers within the solid complexes. The 13C NMR spectra indicated the presence of a mixture of coordination isomers of iron(III) complexes containing the sugar ligand in differently bound forms.
ASJC Scopus subject areas
- Analytical Chemistry
- Nuclear Energy and Engineering
- Radiology Nuclear Medicine and imaging
- Public Health, Environmental and Occupational Health
- Health, Toxicology and Mutagenesis