Spectroscopic evidence for the structure directing role of the solvent in the synthesis of two iron carboxylates

Tadeja Birsa Čelič, Mojca Rangus, Károly Lázár, Venčeslav Kaučič, Nataša Zabukovec Logar

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21 Citations (Scopus)

Abstract

Crystal engineering: The synthesis of the known compounds MIL-100(Fe) and MIL-45(Fe) is characterized by spectroscopy. The products are obtained under identical conditions by varying the solvent from pure water to a mixture of water and acetone. The starting solution, the gel, and the final reaction product were characterized by X-ray absorption spectroscopy (see picture).

Original languageEnglish
Pages (from-to)12490-12494
Number of pages5
JournalAngewandte Chemie - International Edition
Volume51
Issue number50
DOIs
Publication statusPublished - Dec 7 2012

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Keywords

  • EXFAS spectroscopy
  • Moessbauer spectroscopy
  • crystallization
  • metal-organic frameworks

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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