Some chemical properties of (arene)nonacarbonyltetracobalt complexes and the preparation of (arene)octacarbonyltetracobalt trialkylphosphites

A. Sisak, C. Sisak, F. Ungváry, G. Pályi, L. Markó

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

In reactions of Co4(CO)9(arene) with carbon monoxide, phosphines and acetylenes, displacement of the arene takes place and known derivatives of Co4(CO)12 and Co2(CO)8 are formed. With phosphites, however, displacement of one carbon monoxide can be achieved, to give Co4(CO)8(arene)P(OR)3. The same type of complexes can also be prepared by treatment of Co4(CO)11P(OR)3 with arenes.

Original languageEnglish
Pages (from-to)77-83
Number of pages7
JournalJournal of Organometallic Chemistry
Volume90
Issue number1
DOIs
Publication statusPublished - Apr 29 1975

Fingerprint

Carbon Monoxide
Carbon monoxide
chemical properties
carbon monoxide
Chemical properties
Phosphines
Phosphites
preparation
Alkynes
Acetylene
phosphines
acetylene
Derivatives

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

Some chemical properties of (arene)nonacarbonyltetracobalt complexes and the preparation of (arene)octacarbonyltetracobalt trialkylphosphites. / Sisak, A.; Sisak, C.; Ungváry, F.; Pályi, G.; Markó, L.

In: Journal of Organometallic Chemistry, Vol. 90, No. 1, 29.04.1975, p. 77-83.

Research output: Contribution to journalArticle

@article{ea5cbfb60d0b4a22a1a622a7f4dbdab4,
title = "Some chemical properties of (arene)nonacarbonyltetracobalt complexes and the preparation of (arene)octacarbonyltetracobalt trialkylphosphites",
abstract = "In reactions of Co4(CO)9(arene) with carbon monoxide, phosphines and acetylenes, displacement of the arene takes place and known derivatives of Co4(CO)12 and Co2(CO)8 are formed. With phosphites, however, displacement of one carbon monoxide can be achieved, to give Co4(CO)8(arene)P(OR)3. The same type of complexes can also be prepared by treatment of Co4(CO)11P(OR)3 with arenes.",
author = "A. Sisak and C. Sisak and F. Ungv{\'a}ry and G. P{\'a}lyi and L. Mark{\'o}",
year = "1975",
month = "4",
day = "29",
doi = "10.1016/S0022-328X(00)91613-9",
language = "English",
volume = "90",
pages = "77--83",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier",
number = "1",

}

TY - JOUR

T1 - Some chemical properties of (arene)nonacarbonyltetracobalt complexes and the preparation of (arene)octacarbonyltetracobalt trialkylphosphites

AU - Sisak, A.

AU - Sisak, C.

AU - Ungváry, F.

AU - Pályi, G.

AU - Markó, L.

PY - 1975/4/29

Y1 - 1975/4/29

N2 - In reactions of Co4(CO)9(arene) with carbon monoxide, phosphines and acetylenes, displacement of the arene takes place and known derivatives of Co4(CO)12 and Co2(CO)8 are formed. With phosphites, however, displacement of one carbon monoxide can be achieved, to give Co4(CO)8(arene)P(OR)3. The same type of complexes can also be prepared by treatment of Co4(CO)11P(OR)3 with arenes.

AB - In reactions of Co4(CO)9(arene) with carbon monoxide, phosphines and acetylenes, displacement of the arene takes place and known derivatives of Co4(CO)12 and Co2(CO)8 are formed. With phosphites, however, displacement of one carbon monoxide can be achieved, to give Co4(CO)8(arene)P(OR)3. The same type of complexes can also be prepared by treatment of Co4(CO)11P(OR)3 with arenes.

UR - http://www.scopus.com/inward/record.url?scp=0037511893&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037511893&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(00)91613-9

DO - 10.1016/S0022-328X(00)91613-9

M3 - Article

VL - 90

SP - 77

EP - 83

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 1

ER -