Some chemical properties of (arene)nonacarbonyltetracobalt complexes and the preparation of (arene)octacarbonyltetracobalt trialkylphosphites

A. Sisak, C. Sisak, F. Ungváry, G. Pályi, L. Markó

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

In reactions of Co4(CO)9(arene) with carbon monoxide, phosphines and acetylenes, displacement of the arene takes place and known derivatives of Co4(CO)12 and Co2(CO)8 are formed. With phosphites, however, displacement of one carbon monoxide can be achieved, to give Co4(CO)8(arene)P(OR)3. The same type of complexes can also be prepared by treatment of Co4(CO)11P(OR)3 with arenes.

Original languageEnglish
Pages (from-to)77-83
Number of pages7
JournalJournal of Organometallic Chemistry
Volume90
Issue number1
DOIs
Publication statusPublished - Apr 29 1975

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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