Solvolysis kinetics of trimethylsilyl esters of aromatic N-carboxylic acids

R. Szalay, D. Knausz, L. Szakács, K. Újszászy, B. Csákvári, P. Sohár

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Some new trimethylsilyl esters of cyclic and/or aromatic N-carboxylic acids were prepared. Their solvolysis reactions with isopropanol were studied by gas chromatography and by UV spectrophotometry respectively. The pseudo-first-order rate constants, the salt effects and the activation parameters were determined.

Original languageEnglish
Pages (from-to)267-270
Number of pages4
JournalJournal of Organometallic Chemistry
Volume493
Issue number1-2
Publication statusPublished - May 17 1995

Fingerprint

solvolysis
2-Propanol
Spectrophotometry
spectrophotometry
gas chromatography
Carboxylic Acids
Carboxylic acids
carboxylic acids
Gas chromatography
Gas Chromatography
esters
Rate constants
Esters
Salts
Chemical activation
activation
salts
Kinetics
kinetics

Keywords

  • Carbamate
  • Kinetics
  • Silicon
  • Solvolysis
  • Trimethylsilyl

ASJC Scopus subject areas

  • Materials Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Biochemistry

Cite this

Solvolysis kinetics of trimethylsilyl esters of aromatic N-carboxylic acids. / Szalay, R.; Knausz, D.; Szakács, L.; Újszászy, K.; Csákvári, B.; Sohár, P.

In: Journal of Organometallic Chemistry, Vol. 493, No. 1-2, 17.05.1995, p. 267-270.

Research output: Contribution to journalArticle

Szalay, R, Knausz, D, Szakács, L, Újszászy, K, Csákvári, B & Sohár, P 1995, 'Solvolysis kinetics of trimethylsilyl esters of aromatic N-carboxylic acids', Journal of Organometallic Chemistry, vol. 493, no. 1-2, pp. 267-270.
Szalay, R. ; Knausz, D. ; Szakács, L. ; Újszászy, K. ; Csákvári, B. ; Sohár, P. / Solvolysis kinetics of trimethylsilyl esters of aromatic N-carboxylic acids. In: Journal of Organometallic Chemistry. 1995 ; Vol. 493, No. 1-2. pp. 267-270.
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