Solvent and support effects in enantioselective hydrogenation of isophorone with (S)-α,α-diphenyl-2-pyrrolidinemethanol modified palladium

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Asymmetric heterogeneous catalytic hydrogenation of isophorone has been investigated over (S)-α,α-diphenyl-2-pyrrolidinemethanol modified Pd. The influence of solvent and support effects is discussed. The impact of water, acidic and basic additives on enantioselectivity is described.

Original languageEnglish
Pages (from-to)101-109
Number of pages9
JournalReaction Kinetics and Catalysis Letters
Volume79
Issue number1
DOIs
Publication statusPublished - 2003

Fingerprint

Enantioselectivity
Palladium
Hydrogenation
hydrogenation
palladium
Water
water
diphenyl
isophorone

Keywords

  • Chiral modifier
  • Enantioselective
  • Hydrogenation
  • Isophorone

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Catalysis

Cite this

@article{9eb5b750e9de4056b3eabf44891a517d,
title = "Solvent and support effects in enantioselective hydrogenation of isophorone with (S)-α,α-diphenyl-2-pyrrolidinemethanol modified palladium",
abstract = "Asymmetric heterogeneous catalytic hydrogenation of isophorone has been investigated over (S)-α,α-diphenyl-2-pyrrolidinemethanol modified Pd. The influence of solvent and support effects is discussed. The impact of water, acidic and basic additives on enantioselectivity is described.",
keywords = "Chiral modifier, Enantioselective, Hydrogenation, Isophorone",
author = "E. S{\'i}pos and A. Tungler and I. Bitter",
year = "2003",
doi = "10.1023/A:1024163818818",
language = "English",
volume = "79",
pages = "101--109",
journal = "Reaction Kinetics, Mechanisms and Catalysis",
issn = "1878-5190",
publisher = "Springer Netherlands",
number = "1",

}

TY - JOUR

T1 - Solvent and support effects in enantioselective hydrogenation of isophorone with (S)-α,α-diphenyl-2-pyrrolidinemethanol modified palladium

AU - Sípos, E.

AU - Tungler, A.

AU - Bitter, I.

PY - 2003

Y1 - 2003

N2 - Asymmetric heterogeneous catalytic hydrogenation of isophorone has been investigated over (S)-α,α-diphenyl-2-pyrrolidinemethanol modified Pd. The influence of solvent and support effects is discussed. The impact of water, acidic and basic additives on enantioselectivity is described.

AB - Asymmetric heterogeneous catalytic hydrogenation of isophorone has been investigated over (S)-α,α-diphenyl-2-pyrrolidinemethanol modified Pd. The influence of solvent and support effects is discussed. The impact of water, acidic and basic additives on enantioselectivity is described.

KW - Chiral modifier

KW - Enantioselective

KW - Hydrogenation

KW - Isophorone

UR - http://www.scopus.com/inward/record.url?scp=0038175037&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0038175037&partnerID=8YFLogxK

U2 - 10.1023/A:1024163818818

DO - 10.1023/A:1024163818818

M3 - Article

VL - 79

SP - 101

EP - 109

JO - Reaction Kinetics, Mechanisms and Catalysis

JF - Reaction Kinetics, Mechanisms and Catalysis

SN - 1878-5190

IS - 1

ER -