Solution structures of cobalt-rhodium clusters: The identification of a new hexanuclear cobalt-rhodium species

Mary Ann Pearsall, István T. Horváth

Research output: Contribution to journalArticle

Abstract

The thermolysis of Co2Rh2(CO)12 leads to the quantitative formation of Co3Rh3(CO)16. The solution structures of these clusters have been established by IR and low temperature 13C NMR spectroscopy. Co3Rh3(CO)16 reacts with carbon monoxide at moderate pressure to give the equilibrium mixture of Co2Rh2(CO)12 and CoRh(CO)7.

Original languageEnglish
Pages (from-to)187-189
Number of pages3
JournalInorganica Chimica Acta
Volume227
Issue number2
DOIs
Publication statusPublished - Dec 15 1994

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Keywords

  • Cobalt
  • Mixed-metal carbonyl clusters
  • Rhodium

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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