Solution NMR study of methyltin(IV)-cupferronates: Analysis of a unique dismutation reaction and preorganization process

Gábor Tárkányi, Andréa Deák

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Abstract

The solution nuclear magnetic resonence of methyltin(IV)-cuferronates and a unique dismutation reaction and preorganization process was analyzed. The mechanism of the methyl-migrational process was proposed on the basis of solvent induced conformational equilibrium. Kinetic experiments in the NMR was carried out to prove the deduction concerning the reaction mechanism. It was observed that stronger lewis base solvents induced dismutation at markedly faster rates than methanol.

Original languageEnglish
Pages (from-to)3784-3791
Number of pages8
JournalOrganometallics
Volume24
Issue number15
DOIs
Publication statusPublished - Jul 18 2005

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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