Sodium salt of d-glucono-1,5-lactone tosylhydrazone: A ready access to a new glucosylidene carbene precursor

L. Somsák, Jean Pierre Praly, Gérard Descotes

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The sodium salt of 2,3,4,6-tetra-O-benzyl-D-glucono-1,5-lactone tosylhydrazone 4 has been prepared in two steps from 2,3,4,6-tetra-O-benzyl-D-glucopyranose (1). The possibility of using this salt as a glucosylidene carbene precursor has been demonstrated by synthesizing glucosylidene-spirocyclopropanes (2,3,4,6-tetra-O-benzyI-2′(or 3′)-cyano-1-deoxyspiro(D-glucose-1,1′-cyclopropanes]) via photolysis of 4 with acrylonitrile.

Original languageEnglish
Pages (from-to)119-120
Number of pages2
JournalSynlett
Volume1992
Issue number2
DOIs
Publication statusPublished - Feb 1 1992

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Lactones
Cyclopropanes
Salts
Sodium
Acrylonitrile
Photolysis
Glucose
carbene

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Sodium salt of d-glucono-1,5-lactone tosylhydrazone : A ready access to a new glucosylidene carbene precursor. / Somsák, L.; Praly, Jean Pierre; Descotes, Gérard.

In: Synlett, Vol. 1992, No. 2, 01.02.1992, p. 119-120.

Research output: Contribution to journalArticle

Somsák, L. ; Praly, Jean Pierre ; Descotes, Gérard. / Sodium salt of d-glucono-1,5-lactone tosylhydrazone : A ready access to a new glucosylidene carbene precursor. In: Synlett. 1992 ; Vol. 1992, No. 2. pp. 119-120.
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