Single crystal structure determination and refinement of AgZrCu4 and Ag-containing Cu10Zr7 by precession electron diffraction and tomography techniques

I. Cora, P. Pekker, I. Dódony, D. Janovszky

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The Cu-Zr-Ag ternary system belongs to the Cu-based bulk amorphisable alloy systems. The solidification of the amorphisable alloy is still not well-understood. The identification and characterization of the crystal structure of the solidified phases are essential for describing the ternary system. A typical Cu-rich solidified phase in the Cu-Zr-Ag ternary system is the so-called m-phase. The structure of this phase was not known before. Another typical phase is the Ag-containing Cu10Zr7 phase. We determined and refined the crystal structures of single crystals of these two phases by transmission electron microscopyusing precession electron diffraction technique and diffraction tomography (performed by ADT3D software). The determination and refinement procedure was achieved in SIR2008, SIR2011 and SHELXL software packages. In conclusion, precession electron diffraction technique combined with diffraction tomography makes it possible to determine the crystal structure of materials with sub-micrometer sized crystals such as alloys when single crystal X-ray diffraction based structure determination fails.

Original languageEnglish
Pages (from-to)678-683
Number of pages6
JournalJournal of Alloys and Compounds
Volume658
DOIs
Publication statusPublished - Feb 15 2016

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Ternary systems
Electron diffraction
Tomography
Crystal structure
Single crystals
Diffraction
Software packages
Solidification
X ray diffraction
Crystals
Electrons

Keywords

  • Ag-containing CuZr
  • AgCuZr
  • Diffraction tomography
  • Electron crystallography
  • Precession electron diffraction
  • Structure determination

ASJC Scopus subject areas

  • Mechanical Engineering
  • Mechanics of Materials
  • Materials Chemistry
  • Metals and Alloys

Cite this

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title = "Single crystal structure determination and refinement of AgZrCu4 and Ag-containing Cu10Zr7 by precession electron diffraction and tomography techniques",
abstract = "The Cu-Zr-Ag ternary system belongs to the Cu-based bulk amorphisable alloy systems. The solidification of the amorphisable alloy is still not well-understood. The identification and characterization of the crystal structure of the solidified phases are essential for describing the ternary system. A typical Cu-rich solidified phase in the Cu-Zr-Ag ternary system is the so-called m-phase. The structure of this phase was not known before. Another typical phase is the Ag-containing Cu10Zr7 phase. We determined and refined the crystal structures of single crystals of these two phases by transmission electron microscopyusing precession electron diffraction technique and diffraction tomography (performed by ADT3D software). The determination and refinement procedure was achieved in SIR2008, SIR2011 and SHELXL software packages. In conclusion, precession electron diffraction technique combined with diffraction tomography makes it possible to determine the crystal structure of materials with sub-micrometer sized crystals such as alloys when single crystal X-ray diffraction based structure determination fails.",
keywords = "Ag-containing CuZr, AgCuZr, Diffraction tomography, Electron crystallography, Precession electron diffraction, Structure determination",
author = "I. Cora and P. Pekker and I. D{\'o}dony and D. Janovszky",
year = "2016",
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day = "15",
doi = "10.1016/j.jallcom.2015.10.230",
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journal = "Journal of Alloys and Compounds",
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T1 - Single crystal structure determination and refinement of AgZrCu4 and Ag-containing Cu10Zr7 by precession electron diffraction and tomography techniques

AU - Cora, I.

AU - Pekker, P.

AU - Dódony, I.

AU - Janovszky, D.

PY - 2016/2/15

Y1 - 2016/2/15

N2 - The Cu-Zr-Ag ternary system belongs to the Cu-based bulk amorphisable alloy systems. The solidification of the amorphisable alloy is still not well-understood. The identification and characterization of the crystal structure of the solidified phases are essential for describing the ternary system. A typical Cu-rich solidified phase in the Cu-Zr-Ag ternary system is the so-called m-phase. The structure of this phase was not known before. Another typical phase is the Ag-containing Cu10Zr7 phase. We determined and refined the crystal structures of single crystals of these two phases by transmission electron microscopyusing precession electron diffraction technique and diffraction tomography (performed by ADT3D software). The determination and refinement procedure was achieved in SIR2008, SIR2011 and SHELXL software packages. In conclusion, precession electron diffraction technique combined with diffraction tomography makes it possible to determine the crystal structure of materials with sub-micrometer sized crystals such as alloys when single crystal X-ray diffraction based structure determination fails.

AB - The Cu-Zr-Ag ternary system belongs to the Cu-based bulk amorphisable alloy systems. The solidification of the amorphisable alloy is still not well-understood. The identification and characterization of the crystal structure of the solidified phases are essential for describing the ternary system. A typical Cu-rich solidified phase in the Cu-Zr-Ag ternary system is the so-called m-phase. The structure of this phase was not known before. Another typical phase is the Ag-containing Cu10Zr7 phase. We determined and refined the crystal structures of single crystals of these two phases by transmission electron microscopyusing precession electron diffraction technique and diffraction tomography (performed by ADT3D software). The determination and refinement procedure was achieved in SIR2008, SIR2011 and SHELXL software packages. In conclusion, precession electron diffraction technique combined with diffraction tomography makes it possible to determine the crystal structure of materials with sub-micrometer sized crystals such as alloys when single crystal X-ray diffraction based structure determination fails.

KW - Ag-containing CuZr

KW - AgCuZr

KW - Diffraction tomography

KW - Electron crystallography

KW - Precession electron diffraction

KW - Structure determination

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