Shift of Fe 3d band due to chlorine for Fe(III)(salen)

Akio Shigemi, Tatsunori Tochio, Manabu Fujiwara, Jun Kawai, Takayuki Matsushita, Yasuhito Isozumi, T. Mukoyama, Shigero Ikeda

Research output: Contribution to journalArticle

Abstract

The valence band (VB) spectrum of an iron(III) complex, [Fe(salen)Cl], in X-ray photoelectron spectroscopy (XPS) has been calculated with the DV-Xα molecular-orbital method. The influence of chlorine (Cl) in the VB spectrum is examined. It is found that the shallowest binding energy peak in VB spectrum originates from Cl 3p and Fe 3d, and Fe 3d band is deepened due to chlorine for the Fe(III) Schiff base complex in the XPS VB spectra.

Original languageEnglish
Pages (from-to)836-837
Number of pages2
JournalChemistry Letters
Issue number8
Publication statusPublished - 2001

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Chlorine
Valence bands
X ray photoelectron spectroscopy
Schiff Bases
Molecular orbitals
Binding energy
Iron
disalicylaldehyde ethylenediamine

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Shigemi, A., Tochio, T., Fujiwara, M., Kawai, J., Matsushita, T., Isozumi, Y., ... Ikeda, S. (2001). Shift of Fe 3d band due to chlorine for Fe(III)(salen). Chemistry Letters, (8), 836-837.

Shift of Fe 3d band due to chlorine for Fe(III)(salen). / Shigemi, Akio; Tochio, Tatsunori; Fujiwara, Manabu; Kawai, Jun; Matsushita, Takayuki; Isozumi, Yasuhito; Mukoyama, T.; Ikeda, Shigero.

In: Chemistry Letters, No. 8, 2001, p. 836-837.

Research output: Contribution to journalArticle

Shigemi, A, Tochio, T, Fujiwara, M, Kawai, J, Matsushita, T, Isozumi, Y, Mukoyama, T & Ikeda, S 2001, 'Shift of Fe 3d band due to chlorine for Fe(III)(salen)', Chemistry Letters, no. 8, pp. 836-837.
Shigemi A, Tochio T, Fujiwara M, Kawai J, Matsushita T, Isozumi Y et al. Shift of Fe 3d band due to chlorine for Fe(III)(salen). Chemistry Letters. 2001;(8):836-837.
Shigemi, Akio ; Tochio, Tatsunori ; Fujiwara, Manabu ; Kawai, Jun ; Matsushita, Takayuki ; Isozumi, Yasuhito ; Mukoyama, T. ; Ikeda, Shigero. / Shift of Fe 3d band due to chlorine for Fe(III)(salen). In: Chemistry Letters. 2001 ; No. 8. pp. 836-837.
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