Selective oxidation of cyclic hydrocarbons with H2O2 over Ti- and V-containing zeolites and mesoporous catalysts

J. Halász, Alida Éll, Dóra Méhn, Edit Meretei, I. Kiricsi

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Ti- and V-containing MFI, MEL and MCM-41 catalysts were studied in the oxidation of cyclohexane, cyclohexene, naphthalene, tetralin, decalin and phenol with H2O2. Although TS-1 and TS-2 exhibited the highest activity and selectivity in the oxidation of n-hexane and 1-hexene, cyclohexene could only be oxidized effectively on the MCM-41 silicates. Since the oxidation of condensed aromatic systems over Ti- and V-containing MFI and MEL zeolites runs to difficulties, MCM-41 type catalysts may be offered for these reactions.

Original languageEnglish
Pages (from-to)371-376
Number of pages6
JournalReaction Kinetics and Catalysis Letters
Volume74
Issue number2
DOIs
Publication statusPublished - 2001

Fingerprint

Cyclic Hydrocarbons
cyclic hydrocarbons
Zeolites
Multicarrier modulation
zeolites
Hydrocarbons
catalysts
Oxidation
oxidation
Catalysts
Silicates
hexenes
Naphthalene
Cyclohexane
Phenol
Hexane
naphthalene
cyclohexane
phenols
Phenols

Keywords

  • Cyclic hydrocarbons
  • MEL and MCM-41
  • Oxidation
  • Ti- and V-containing MFI

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

Cite this

Selective oxidation of cyclic hydrocarbons with H2O2 over Ti- and V-containing zeolites and mesoporous catalysts. / Halász, J.; Éll, Alida; Méhn, Dóra; Meretei, Edit; Kiricsi, I.

In: Reaction Kinetics and Catalysis Letters, Vol. 74, No. 2, 2001, p. 371-376.

Research output: Contribution to journalArticle

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