Scaling of some chemical properties of tetrahedral and octahedral molecules plus almost spherical C and B cages

N. H. March, Á Nagy

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Abstract

It is shown that for tetrahedral and octahedral molecules the quantity aRe/N1/3 is quadratic in the ratio z/N, where Re is the equilibrium bond length, ze is the central charge and N is the total number of electrons. Some scaling properties for the 'breathing' force constant k are proposed for a series of 5 tetrachlorides.

Original languageEnglish
Pages (from-to)2268-2274
Number of pages7
JournalJournal of Mathematical Chemistry
Volume49
Issue number10
DOIs
Publication statusPublished - Nov 1 2011

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Keywords

  • Scaling
  • Tetrahedral and octahedral molecules

ASJC Scopus subject areas

  • Chemistry(all)
  • Applied Mathematics

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