Rydberg bands in the near UV spectra of substituted pyrroles

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Vapour phase and solution spectra of pyrrole and three of its derivatives were investigated in the near UV region. Band systems disappearing from the solution spectra could be assigned to Rydberg transitions if the band profiles were compared with those of the corresponding UPS bands and with other Rydbergs of the same molecule. In the case of each compound, four Rydbergs originating from the uppermost π orbital were found, terminating at 3s, 3p and 3p′, 3d Rydberg orbitals.

Original languageEnglish
Pages (from-to)233-237
Number of pages5
JournalJournal of Molecular Structure
Volume243
Issue number3-4
DOIs
Publication statusPublished - 1991

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Pyrroles
pyrroles
orbitals
Vapors
Derivatives
stopping
Molecules
vapor phases
profiles
molecules

ASJC Scopus subject areas

  • Structural Biology
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Materials Science (miscellaneous)
  • Atomic and Molecular Physics, and Optics

Cite this

Rydberg bands in the near UV spectra of substituted pyrroles. / Nyulászi, L.

In: Journal of Molecular Structure, Vol. 243, No. 3-4, 1991, p. 233-237.

Research output: Contribution to journalArticle

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