Role of weighting in parameter estimation from solid-fluid supercritical equilibrium data

A. Deák, S. Kemény

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

As an example, the solubility of naphthalene in supercritical CO and C2H4were chosen. Two parameter estimation criteria were compared: use of constant relative error and the maximum likelihood criterion, the latter involves the use of weights derived from the error propagation law. It was found that σ2 Δy is very far from being proportional to y2, therefore the use of constant relative error is not justified. In the case of the given solid-fluid equilibrium examples, weights based on constant relative error assumption overemphasize the steep part of the curve where all models fail. None of the models examined were able to describe C2H4-naphthalene equilibrium. For CO2-naphthalene the BMRK model proved to be better than the other equations of state investigated.

Original languageEnglish
Pages (from-to)171-190
Number of pages20
JournalFluid Phase Equilibria
Volume100
Issue numberC
DOIs
Publication statusPublished - Sep 15 1994

Fingerprint

Supercritical fluids
supercritical fluids
Parameter estimation
Naphthalene
naphthalene
Carbon Monoxide
Equations of state
Maximum likelihood
equations of state
solubility
Solubility
Fluids
propagation
fluids
curves

Keywords

  • equation of state
  • methods of calculation
  • mixtures
  • solid - fluid equilibria
  • theory

ASJC Scopus subject areas

  • Fluid Flow and Transfer Processes
  • Physical and Theoretical Chemistry

Cite this

Role of weighting in parameter estimation from solid-fluid supercritical equilibrium data. / Deák, A.; Kemény, S.

In: Fluid Phase Equilibria, Vol. 100, No. C, 15.09.1994, p. 171-190.

Research output: Contribution to journalArticle

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