Role of Hansen solubility parameters in solid phase extraction

K. Bielicka-Daszkiewicz, A. Voelkel, M. Pietrzyńska, K. Héberger

Research output: Contribution to journalArticle

18 Citations (Scopus)


The sorbent-eluent systems combined from eight polymeric sorbents and seven solvents as eluents were used for the extraction of phenol and its oxidation products from water samples. The individual interactions between sorbents, eluents and analytes were characterized by Hansen solubility parameters. Principal components analysis (PCA) was used for revealing the dominant interactions (dispersive, polar, and hydrogen bonding type) in sorbent-analyte-eluent systems. The importance of solubility parameters was also determined by a novel procedure based on sum of ranking differences (SRD). Although PCA and ranking by SRD are based on different principles and calculations, they have provided very similar results. The recovery in a given system has been predicted from the magnitudes of mutual interactions (sorbent-analyte, sorbent-eluent, analyte-eluent) by multiple linear regression.

Original languageEnglish
Pages (from-to)5564-5570
Number of pages7
JournalJournal of Chromatography A
Issue number35
Publication statusPublished - Aug 2010


  • Chemometrics
  • Hansen solubility parameters
  • Multiple linear regression
  • Pattern recognition
  • Principal component analysis

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Organic Chemistry

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