Ring-chain tautomerism of 2-aryl-substituted imidazolidines

L. Lázár, Anikó Göblyös, Ferenc Evanics, G. Bernáth, F. Fülöp

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

N-Methyl-, N-ethyl-, N-(n-propyl)-, N-(iso-propyl)- and N-phenyl-2- arylimidazolidines proved to be ring-chain tautomeric mixtures in CDCl3. The ratios of the open and ring forms in the tautomeric equilibria of these compounds is described by the equation log K(x) = pσ+ + log K(x)-(II), used earlier for the ring-chain equilibria of saturated 2-aryl-1,3-O,N- heterocycles. These are the first examples among 2-arylimidazolidines of ring-chain tautomeric processes characterized by a Hammett-type correlation.

Original languageEnglish
Pages (from-to)13639-13644
Number of pages6
JournalTetrahedron
Volume54
Issue number44
DOIs
Publication statusPublished - Oct 29 1998

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Imidazolidines

Keywords

  • Diamines
  • Electronic and steric effects
  • Imidazolidines
  • Tautomerism

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Ring-chain tautomerism of 2-aryl-substituted imidazolidines. / Lázár, L.; Göblyös, Anikó; Evanics, Ferenc; Bernáth, G.; Fülöp, F.

In: Tetrahedron, Vol. 54, No. 44, 29.10.1998, p. 13639-13644.

Research output: Contribution to journalArticle

Lázár, L. ; Göblyös, Anikó ; Evanics, Ferenc ; Bernáth, G. ; Fülöp, F. / Ring-chain tautomerism of 2-aryl-substituted imidazolidines. In: Tetrahedron. 1998 ; Vol. 54, No. 44. pp. 13639-13644.
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