Rhodium(I)-sulfonated-bdpp catalysed asymmetric hydrogenation of imines in aqueous-organic two-phase solvent systems

J. Bakos, Árpád Orosz, Bálint Heil, Mohamed Laghmari, Paul Lhoste, Denis Sinou

Research output: Contribution to journalArticle

125 Citations (Scopus)

Abstract

The imines ArC(Me)=NCH2Ph (Ar = Ph, 2-MeO-C6H 4, 3-MeO-C6H4, 4-MeO-C6H 4) are hydrogenated to the corresponding amines with extremely high enantioselectivities up to 96% under very mild conditions, using rhodium complexes associated with sulfonated bdpp.

Original languageEnglish
Pages (from-to)1684-1685
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number23
DOIs
Publication statusPublished - 1991

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Rhodium
Imines
Hydrogenation
Enantioselectivity
Amines

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

Rhodium(I)-sulfonated-bdpp catalysed asymmetric hydrogenation of imines in aqueous-organic two-phase solvent systems. / Bakos, J.; Orosz, Árpád; Heil, Bálint; Laghmari, Mohamed; Lhoste, Paul; Sinou, Denis.

In: Journal of the Chemical Society, Chemical Communications, No. 23, 1991, p. 1684-1685.

Research output: Contribution to journalArticle

Bakos, J. ; Orosz, Árpád ; Heil, Bálint ; Laghmari, Mohamed ; Lhoste, Paul ; Sinou, Denis. / Rhodium(I)-sulfonated-bdpp catalysed asymmetric hydrogenation of imines in aqueous-organic two-phase solvent systems. In: Journal of the Chemical Society, Chemical Communications. 1991 ; No. 23. pp. 1684-1685.
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