Revisiting the reaction of phosphole oxide dimers with borane-dimethylsulfide

Tamara Kovács, Dóra Cseresnyés, L. Drahos, G. Keglevich

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The selective reduction and boronation of the P-phenyl phosphole oxide dimer applying BH3 ·SMe2 as the reagent was investigated. The optimized protocol allowing the P˭O→P→BH3 conversion at 26°C in concentrated CH2Cl2 solution could be well extended also to a series of P-alkyl phosphole oxide dimers.

Original languageEnglish
Pages (from-to)695-699
Number of pages5
JournalPhosphorus, Sulfur and Silicon and the Related Elements
Volume192
Issue number6
DOIs
Publication statusPublished - Jun 3 2017

Keywords

  • 7-phosphanorbornene oxide
  • borane
  • P-borane
  • Phosphole oxide dimer
  • reduction

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Inorganic Chemistry

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