Resolution of P-stereogenic P-heterocycles via the formation of diastereomeric molecular and coordination complexes (a review)

Péter Bagi, Viktória Ujj, M. Czugler, E. Fogassy, G. Keglevich

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

TADDOL derivatives and the Ca2+-salts of tartaric acid derivatives were found to be versatile and generally applicable resolving agents for the preparation of the enantiomers of P-stereogenic heterocyclic phosphine oxides and phosphinates via the formation of the corresponding diastereomeric molecular and coordination complexes. A few of the diastereomeric intermediates were characterized by single crystal X-ray crystallography to gain insights into the binding mode of the corresponding heterocyclic phosphine oxide ("guest") and the resolving agent ("host") and to study the underlying phenomenon of enantiomeric recognition.

Original languageEnglish
Pages (from-to)1823-1842
Number of pages20
JournalDalton Transactions
Volume45
Issue number5
DOIs
Publication statusPublished - 2016

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phosphine
Coordination Complexes
Oxides
Derivatives
Enantiomers
X ray crystallography
Salts
Single crystals

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Resolution of P-stereogenic P-heterocycles via the formation of diastereomeric molecular and coordination complexes (a review). / Bagi, Péter; Ujj, Viktória; Czugler, M.; Fogassy, E.; Keglevich, G.

In: Dalton Transactions, Vol. 45, No. 5, 2016, p. 1823-1842.

Research output: Contribution to journalArticle

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