Resolution of 5- and 6-membered p-heterocycles: Racemic and optically active platinum(ii)-3-phospholene complexes

Péter Bagi, Tamara Kovács, Andrea Laki, András Fekete, Elemér Fogassy, György Keglevich

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Methods were developed for the resolution of several five- and six-membered phosphorus heterocycles (1c-e, 2, 4). It was investigated if the optical activity is preserved during the 1a→2→3→4 reaction sequence. Racemic and optically active 1b-e 3-phospholene 1-oxides were converted to the corresponding platinum-complexes (10b-e), which are potential catalysts.

Original languageEnglish
Pages (from-to)36-38
Number of pages3
JournalPhosphorus, Sulfur and Silicon and the Related Elements
Volume188
Issue number1-3
DOIs
Publication statusPublished - Jan 1 2013

Keywords

  • 1,2,3,6-tetrahydrophosphinine 1-oxide a resolution
  • 1,2-dihydrophosphinine oxide
  • 3-Phospholene oxide
  • 3-phosphabicyclo[3.1.0]hexane oxide
  • platinum complex

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Inorganic Chemistry

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