Remarks on the energetics of interfaces exhibiting constant phase element behaviour

G. Láng, K. E. Heusler

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Abstract

The energetics of electrified interfaces exhibiting constant phase element (CPE) behaviour is discussed. In the double layer region energy can be dissipated in various ways other than by charge transfer. Therefore, contrary to the statement in Zoltowski., J. Electroanal. Chem. 443 (1998) 149, an electrode with a double layer of CPE character can be an ideally polarisable electrode.

Original languageEnglish
Pages (from-to)257-260
Number of pages4
JournalJournal of Electroanalytical Chemistry
Volume457
Issue number1-2
DOIs
Publication statusPublished - Oct 15 1998

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Keywords

  • CPE
  • Energy dissipation
  • Ideally polarisable electrode
  • Impedance spectroscopy

ASJC Scopus subject areas

  • Analytical Chemistry
  • Chemical Engineering(all)
  • Electrochemistry

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