Relaxometric determination of binding between Mn(II)-UDP and Mn(II)-UDP-glucose in aqueous solution

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Abstract

The applicability of relaxometry for the determination of formation constants of Mn(II)-UDP (log K = 3.78) and Mn(II)-UDP-glucose (log K = 2.98) complexes is demonstrated. The obtained value indicates a well-defined interaction between Mn(II) and UDP-glucose in aqueous solution (pH = 5.50) with ΔG = -4.07 kcal/mol.

Original languageEnglish
Pages (from-to)68-72
Number of pages5
JournalCarbohydrate Research
Volume368
DOIs
Publication statusPublished - Mar 7 2013

Keywords

  • Complex
  • Manganese(II)
  • Relaxometry
  • Stability constant
  • UDP-glucose

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Organic Chemistry

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