Regioselective suzuki-miyaura reactions of aromatic bis-triflates

Electronic versus steric effects

Zahid Hassan, T. Patonay, Peter Langer

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Suzuki-Miyaura reactions of aromatic bis-triflates, readily available from the corresponding hydroxylated arenes, often proceed with excellent regioselectivity and provide a convenient approach to various arylated benzene derivatives, such as biphenyls, terphenyls, and arylated benzophenones, naphthalenes, xanthones, flavones, coumarins, anthraquinones, tetralones, and fluorenones. The regioselectivity is controlled by steric and electronic parameters and strongly depends on the structure of the substrates. 1 Introduction 2 Benzoates, Phthalates, and Naphthoates 3 Benzophenones and Diphenyl Sulfones 4 Xanthones and Thioxanthones 5 Flavones and Coumarins 6 Anthraquinones, Tetralones, and Fluorenones 7 Conclusion.

Original languageEnglish
Pages (from-to)412-423
Number of pages12
JournalSynlett
Volume24
Issue number4
DOIs
Publication statusPublished - 2013

Fingerprint

Tetralones
Xanthones
Flavones
Regioselectivity
Anthraquinones
Benzophenones
Naphthalenes
Benzene Derivatives
Coumarins
Sulfones
Benzoates
Substrates
diphenyl

Keywords

  • bis-triflates
  • catalysis
  • palladium
  • regioselectivity
  • Suzuki-Miyaura reaction

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Regioselective suzuki-miyaura reactions of aromatic bis-triflates : Electronic versus steric effects. / Hassan, Zahid; Patonay, T.; Langer, Peter.

In: Synlett, Vol. 24, No. 4, 2013, p. 412-423.

Research output: Contribution to journalArticle

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