Reductive cleavage of COH bonds in allyl position--formation of gaseous products in the course of the cathodic reduction of some simple unsaturated alcohols

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Abstract

The problem of the reductive cleavage of COH bonds in allyl position has been considered starting from the literature data concerning the behaviour of allyl alcohol. The formation of hydrocarbons has been shown in the case of the electroreduction of crotyl alcohol, 2-butene-1,4-diol, propargyl alcohol, 2-butyne-1,4-diol and 1-butyne-3-ol. The composition of the gaseous products was analyzed, current efficiency values with respect to the hydrocarbon formation were calculated. Schemes for the reduction path were given.

Original languageEnglish
Pages (from-to)101-108
Number of pages8
JournalJournal of Electroanalytical Chemistry
Volume101
Issue number1
Publication statusPublished - Jul 25 1979

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Hydrocarbons
Alcohols
Butenes
Chemical analysis
penitricin C
crotonyl alcohol
allyl alcohol
2-butyne-1,4-diol
propargyl alcohol

ASJC Scopus subject areas

  • Electrochemistry
  • Analytical Chemistry
  • Chemical Engineering(all)

Cite this

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abstract = "The problem of the reductive cleavage of COH bonds in allyl position has been considered starting from the literature data concerning the behaviour of allyl alcohol. The formation of hydrocarbons has been shown in the case of the electroreduction of crotyl alcohol, 2-butene-1,4-diol, propargyl alcohol, 2-butyne-1,4-diol and 1-butyne-3-ol. The composition of the gaseous products was analyzed, current efficiency values with respect to the hydrocarbon formation were calculated. Schemes for the reduction path were given.",
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AU - Horányi, G.

AU - Inzelt, G.

AU - Torkos, K.

PY - 1979/7/25

Y1 - 1979/7/25

N2 - The problem of the reductive cleavage of COH bonds in allyl position has been considered starting from the literature data concerning the behaviour of allyl alcohol. The formation of hydrocarbons has been shown in the case of the electroreduction of crotyl alcohol, 2-butene-1,4-diol, propargyl alcohol, 2-butyne-1,4-diol and 1-butyne-3-ol. The composition of the gaseous products was analyzed, current efficiency values with respect to the hydrocarbon formation were calculated. Schemes for the reduction path were given.

AB - The problem of the reductive cleavage of COH bonds in allyl position has been considered starting from the literature data concerning the behaviour of allyl alcohol. The formation of hydrocarbons has been shown in the case of the electroreduction of crotyl alcohol, 2-butene-1,4-diol, propargyl alcohol, 2-butyne-1,4-diol and 1-butyne-3-ol. The composition of the gaseous products was analyzed, current efficiency values with respect to the hydrocarbon formation were calculated. Schemes for the reduction path were given.

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