Redox properties of cobalt(II) complexes with isoindoline-based ligands

J. Pap, Balázs Kripli, Michel Giorgi, J. Kaizer, G. Speier

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Cobalt bis-(N-arylimino)isoindolinates undergo electrostatic interactions with DNA or react with alkyl hydroperoxides to form ketones and alcohols. Redox behavior of the metal center should affect such reactivities; therefore, six neutral CoII(L)2 complexes with L = bis-(N-arylimino) isoindolinates have been synthesized to elucidate the effect of the aryl substituents on the redox potential of the metal center. Redox properties of various MII(L)2 complexes (M = Mn, Fe, Co, Ni) are compared. Moreover, data are presented on the dismutation rates of superoxide radical anion (a knowingly sensitive reagent on the redox properties of the metal center) in the presence of the various CoII(L)2 complexes among identical conditions.

Original languageEnglish
Pages (from-to)481-487
Number of pages7
JournalTransition Metal Chemistry
Volume36
Issue number5
DOIs
Publication statusPublished - Aug 2011

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Cobalt
Ligands
Metals
Coulomb interactions
Ketones
Superoxides
Hydrogen Peroxide
Anions
Alcohols
DNA
Negative ions
Oxidation-Reduction

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Materials Chemistry
  • Metals and Alloys

Cite this

Redox properties of cobalt(II) complexes with isoindoline-based ligands. / Pap, J.; Kripli, Balázs; Giorgi, Michel; Kaizer, J.; Speier, G.

In: Transition Metal Chemistry, Vol. 36, No. 5, 08.2011, p. 481-487.

Research output: Contribution to journalArticle

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