Recent Developments of FT-IR and Raman Spectroscopy in Coordination Chemistry

J. Mink, I. Pápai, M. Gál, P. L. Goggin

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

The nature of the bond between a metal and an unsaturated hydrocarbon is one of the most fundamental and significant problems in coordination chemistry. In spite of wide structural and spectroscopic studies of olephinic π-complexes a number of fundamental spectroscopic properties have not been clearified yet. Reinvestigation of FT-IR and Raman spectra of K[Pt(C2H4)Cl3] and K[Pt(C2H4)Cl3].H20 in both the solid phase and water/HCl solution suggests some modification of widely accepted assignments. Skeletal modes of [NBu4][Pt(C2H4)Br3], [NBu4][Pd(C2H4)Cl3] and their C2D4derivatives have been measured and assigned. A new model for the normal coordinate treatment of π-complexes has been adopted to calculate metal-ligand force constants.

Original languageEnglish
Pages (from-to)973-978
Number of pages6
JournalPure and Applied Chemistry
Volume61
Issue number5
DOIs
Publication statusPublished - Jan 1 1989

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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