Chlorination of ethylene with chlorine in C2H4Cl2 solvent, with and without FeCl3 catalyst, was studied in the temperature range from 293 to 308 K. Simultaneous addition and substitution were detected. The rate constants were determined by numerical integration of kinetic equations. Activation energies and preexponential factors were calculated as well.
ASJC Scopus subject areas
- Physical and Theoretical Chemistry