Reaction products from αβ-unsaturated ketones and aliphatic diamines or dithiols

Kálmán Hideg, Douglas Lloyd

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

Ethylenediamine reacts with αβ-unsaturated ketones to give either tetrahydrodiazepines, tetra-azacyclotetra-decadienes, or uncyclised adducts derived from one molar equivalent of amine and two of enone. 1,3-Diaminopropane gave either a hexahydrodiazocine or an uncyclised adduct. 1,6-Diaminohexane, piperazine, or ethane-1,2-dithiol gave only uncyclised adducts. Some reactions of the uncyclised adducts are mentioned.

Original languageEnglish
Pages (from-to)3441-3445
Number of pages5
JournalJournal of the Chemical Society C: Organic Chemistry
DOIs
Publication statusPublished - Jan 1 1971

ASJC Scopus subject areas

  • Organic Chemistry

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