Reaction of octacarbonyldicobalt with the free radicals galvinoxyl and 2,2-diphenyl-1-picrylhydrazyl. Attempts to scavenge the tetracarbonylcobalt radical

Róbert Tuba, F. Ungváry

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The addition of galvinoxyl or 2,2-diphenyl-1-picrylhydrazyl to octacarbonyldicobalt in n-octane solution results in the loss of all carbon monoxide ligands and the formation of Co(II)-containing products.

Original languageEnglish
Pages (from-to)308-312
Number of pages5
JournalInorganica Chimica Acta
Volume334
DOIs
Publication statusPublished - May 30 2002

Fingerprint

octanes
Carbon Monoxide
Free radicals
Carbon monoxide
free radicals
carbon monoxide
Free Radicals
Ligands
ligands
products
octane
galvinoxyl
2,2-diphenyl-1-picrylhydrazyl

Keywords

  • 1,1-Diphenyl-2-picrylhydrazine
  • 2,2-Diphenyl-1-picrylhydrazyl
  • Galvinoxyl
  • Hydroxygalvinol
  • Octacarbonyldicobalt
  • Tetracarbonylcobalt radical

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

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title = "Reaction of octacarbonyldicobalt with the free radicals galvinoxyl and 2,2-diphenyl-1-picrylhydrazyl. Attempts to scavenge the tetracarbonylcobalt radical",
abstract = "The addition of galvinoxyl or 2,2-diphenyl-1-picrylhydrazyl to octacarbonyldicobalt in n-octane solution results in the loss of all carbon monoxide ligands and the formation of Co(II)-containing products.",
keywords = "1,1-Diphenyl-2-picrylhydrazine, 2,2-Diphenyl-1-picrylhydrazyl, Galvinoxyl, Hydroxygalvinol, Octacarbonyldicobalt, Tetracarbonylcobalt radical",
author = "R{\'o}bert Tuba and F. Ungv{\'a}ry",
year = "2002",
month = "5",
day = "30",
doi = "10.1016/S0020-1693(02)00853-8",
language = "English",
volume = "334",
pages = "308--312",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
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T1 - Reaction of octacarbonyldicobalt with the free radicals galvinoxyl and 2,2-diphenyl-1-picrylhydrazyl. Attempts to scavenge the tetracarbonylcobalt radical

AU - Tuba, Róbert

AU - Ungváry, F.

PY - 2002/5/30

Y1 - 2002/5/30

N2 - The addition of galvinoxyl or 2,2-diphenyl-1-picrylhydrazyl to octacarbonyldicobalt in n-octane solution results in the loss of all carbon monoxide ligands and the formation of Co(II)-containing products.

AB - The addition of galvinoxyl or 2,2-diphenyl-1-picrylhydrazyl to octacarbonyldicobalt in n-octane solution results in the loss of all carbon monoxide ligands and the formation of Co(II)-containing products.

KW - 1,1-Diphenyl-2-picrylhydrazine

KW - 2,2-Diphenyl-1-picrylhydrazyl

KW - Galvinoxyl

KW - Hydroxygalvinol

KW - Octacarbonyldicobalt

KW - Tetracarbonylcobalt radical

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EP - 312

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

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