Reaction of HCo(CO)4 with olefins. Effect of Co2(CO)8

Ferenc Ungváry, László Markó

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

Dicobalt octacarbonyl catalyzes the formation of acylcobalt tetracarbonyls and paraffins from olefins and cobalt tetracarbonyl hydride, presumably by generating radical species. The relativereactivities of CO and HCo(CO)4 towards an alkylcobalt carbonyl determine the carbonylation/hydrogenation ratio.

Original languageEnglish
Pages (from-to)397-400
Number of pages4
JournalJournal of Organometallic Chemistry
Volume219
Issue number3
DOIs
Publication statusPublished - Oct 27 1981

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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