Reaction of cyclopropane carboxylic acid derivatives with sulphur tetrafluoride - An example of a diastereoselective ring opening

Z. Hell, Z. Finta, W. Dmowski, F. Faigl, Yu M. Pustovit, L. Toke, V. Harmat

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9 Citations (Scopus)

Abstract

Cyclopropane carboxylic acid derivatives can be converted into trifluoromethyl group-containing compounds using SF4. In the case of a bicyclic cyclopropane carboxylic acid lactone, similar treatment with sulphur tetrafluoride resulted in the cyclopropane ring opening in a diastereoselective manner.

Original languageEnglish
Pages (from-to)297-301
Number of pages5
JournalJournal of Fluorine Chemistry
Volume104
Issue number2
DOIs
Publication statusPublished - Jul 2000

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Keywords

  • Cyclopropane
  • Ring opening
  • Sulphur tetrafluoride

ASJC Scopus subject areas

  • Biochemistry
  • Environmental Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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